Introduction to Quantum Mechanics with Applications to Chemistry (Paperback) (量子力學導論:化學應用)
Linus Pauling, E. Bright Wilson Jr.
- 出版商: Dover Publications
- 出版日期: 1985-03-01
- 售價: $960
- 貴賓價: 9.5 折 $912
- 語言: 英文
- 頁數: 496
- 裝訂: Paperback
- ISBN: 0486648710
- ISBN-13: 9780486648712
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相關分類:
化學 Chemistry、量子 Quantum
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相關主題
商品描述
When this classic text was first published in 1935, it fulfilled the goal of its authors "to produce a textbook of practical quantum mechanics for the chemist, the experimental physicist, and the beginning student of theoretical physics." Although many who are teachers today once worked with the book as students, the text is still as valuable for the same undergraduate audience.
Two-time Nobel Prize winner Linus Pauling, Research Professor at the Linus Pauling Institute of Science and Medicine, Palo Alto, California, and E. Bright Wilson, Jr., Professor Emeritus of Chemistry at Harvard University, provide a readily understandable study of "wave mechanics," discussing the Schrodinger wave equation and the problems which can be solved with it. Extensive knowledge of mathematics is not required, although the student must have a grasp of elementary mathematics through the calculus. Pauling and Wilson begin with a survey of classical mechanics, including Newton's equations of motion in the Lagrangian form, and then move on to the "old" quantum theory, developed through the work of Planck, Einstein and Bohr. This analysis leads to the heart of the book ― an explanation of quantum mechanics which, as Schrodinger formulated it, "involves the renunciation of the hope of describing in exact detail the behavior of a system." Physics had created a new realm in which classical, Newtonian certainties were replaced by probabilities ― a change which Heisenberg's uncertainty principle (described in this book) subsequently reinforced.
With clarity and precision, the authors guide the student from topic to topic, covering such subjects as the wave functions for the hydrogen atom, perturbation theory, the Pauli exclusion principle, the structure of simple and complex molecules, Van der Waals forces, and systems in thermodynamic equilibrium. To insure that the student can follow the mathematical derivations, Pauling and Wilson avoid the "temptation to condense the various discussions into shorter and perhaps more elegant forms" appropriate for a more advanced audience. Introduction to Quantum Mechanics is a perfect vehicle for demonstrating the practical application of quantum mechanics to a broad spectrum of chemical and physical problems.
商品描述(中文翻譯)
當這本經典教材於1935年首次出版時,它實現了作者的目標,即「為化學家、實驗物理學家和理論物理學初學者製作一本實用的量子力學教科書」。雖然今天許多教師曾經以學生身份使用過這本書,但對於同樣的大學本科學生群體來說,這本教材仍然具有價值。
兩次諾貝爾獎得主、加州帕羅奧圖的林納斯·鮑林研究所的研究教授林納斯·鮑林和哈佛大學化學名譽教授E·布萊特·威爾遜提供了一個易於理解的「波動力學」研究,討論了薛定谔波動方程及其可解決的問題。雖然不需要廣泛的數學知識,但學生必須對微積分等基礎數學有所了解。鮑林和威爾遜從經典力學的概述開始,包括拉格朗日形式的牛頓運動方程,然後轉向「舊」量子理論,該理論是通過普朗克、愛因斯坦和玻爾的工作發展起來的。這種分析導致了本書的核心部分 - 量子力學的解釋,正如薛定谔所形容的那樣,「放棄了對系統行為進行精確描述的希望」。物理學創造了一個新的領域,其中古典的牛頓確定性被概率所取代 - 這種變化在海森堡的不確定性原理(本書中有描述)之後得到了加強。
作者以清晰而精確的方式引導學生從一個主題轉向另一個主題,涵蓋了氫原子的波函數、微擾理論、泡利排斥原理、簡單和複雜分子的結構、范德華力和熱力學平衡系統等主題。為了確保學生能夠理解數學推導,鮑林和威爾遜避免了「將各種討論縮短成更簡潔、更優雅的形式」的誘惑,這種形式適用於更高級的讀者群體。《量子力學導論》是展示量子力學在化學和物理問題的廣泛領域中的實際應用的完美工具。