Orbital Approach to the Electronic Structure of Solids (Hardcover)

Enric Canadell, Marie-Liesse Doublet, Christophe Iung

  • 出版商: Oxford University
  • 出版日期: 2012-03-21
  • 售價: $1,400
  • 貴賓價: 9.8$1,372
  • 語言: 英文
  • 頁數: 352
  • 裝訂: Hardcover
  • ISBN: 0199534934
  • ISBN-13: 9780199534937
  • 下單後立即進貨 (約5~7天)

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商品描述

<內容簡介>

* Presents an original approach to the electronic structure of solids and outlines the strong ties between molecules and solids
* Illustrates different concepts and main ideas with reference to real materials
* Provides useful learning tool for students with different backgrounds (physics, chemistry, materials science)
* Will appeal to both students and researchers willing to understand results of quantitative calculations or to rationalize experimental observations in solid state and materials science
* Richly illustrated, with ample tutorial material
* Solutions to the exercises provided

This book provides an intuitive yet sound understanding of how structure and properties of solids may be related. The natural link is provided by the band theory approach to the electronic structure of solids. The chemically insightful concept of orbital interaction and the essential machinery of band theory are used throughout the book to build links between the crystal and electronic structure of periodic systems. In such a way, it is shown how important tools for understanding properties of solids like the density of states, the Fermi surface etc. can be qualitatively sketched and used to either understand the results of quantitative calculations or to rationalize experimental observations. Extensive use of the orbital interaction approach appears to be a very efficient way of building bridges between physically and chemically based notions to understand the structure and properties of solids.

<章節目錄>

1: Elementary introduction to the transport properties of solids

2: Electronic structure of molecules: use of the symmetry

3: Electronic Structure of One-dimensional Systems: Basic Notions

4: Electronic First-order Peierls distortions in periodic 1D systems

5: Application to trans-polyacetylene

6: Handling the symmetry in 1D compounds

7: Application to polyacene

8: Electronic structure of selected inorganic chains

9: Electronic structure of 2D and 3D systems

10: Density of States

11: Fermi surface and Low Dimensional Metals

12: Electron repulsion

商品描述(中文翻譯)

內容簡介
* 提出了一種原創的方法來探討固體的電子結構,並概述了分子與固體之間的緊密聯繫
* 以實際材料為參考,說明不同的概念和主要思想
* 為不同背景的學生(物理、化學、材料科學)提供有用的學習工具
* 對於希望理解定量計算結果或合理化固態和材料科學中實驗觀察的學生和研究人員都具有吸引力
* 圖文並茂,提供豐富的教學材料
* 提供習題的解答

本書提供了一種直觀而又合理的理解方式,說明固體的結構和性質之間的關聯。這一自然聯繫是通過帶隙理論來探討固體的電子結構。書中貫穿使用了化學上有洞察力的軌道相互作用概念和帶隙理論的基本機制,以建立晶體和周期系統的電子結構之間的聯繫。以此方式,展示了如何定性地描繪和使用理解固體性質的重要工具,如態密度、費米面等,來理解定量計算的結果或合理化實驗觀察。廣泛使用軌道相互作用的方法被認為是一種非常有效的方式,能夠在物理和化學基礎的概念之間架起橋樑,以理解固體的結構和性質。

章節目錄
1: 固體的傳輸性質初步介紹

2: 分子的電子結構:對稱性的應用

3: 一維系統的電子結構:基本概念

4: 週期性一維系統中的電子一階佩爾斯畸變

5: 應用於反式聚乙炔

6: 處理一維化合物中的對稱性

7: 應用於聚烯

8: 選定無機鏈的電子結構

9: 二維和三維系統的電子結構

10: 態密度

11: 費米面和低維金屬

12: 電子排斥